报告题目：Li-N-H System for Hydrogen Storage: An Investigation on Reaction Mechanism and Catalytic Effect
报告人：Hokkaido University, Sapporo, Japan
报告时间：2015年10月15号 9:00 a.m.
报告地点：宝山校区E408（上海大学材料基因组工程研究院学术报告厅）
邀请人：李谦 教授
摘要 Abstract
Hydrogen storage is a big challenge for a future hydrogen energy society. The U.S. Department of Energy (DOE) set some technical targets for on-board hydrogen storage systems. The ultimate targets for system gravimetric and volumetric capacities of hydrogen are set to 6.0 wt% and 65 g L-1 in 2020, respectively. Among the hydrogen storage materials, Li-N-H system is an attractive hydrogen storage material, which can be reversible and absorb a large amount of hydrogen (6.5wt. %). In addition, catalyst can improve its kinetics [1]. However, the reaction mechanism and the catalytic effect have not been clearly clarified. In this research we aimed to identify the formation site of LiH and LiNH2 in the process of de/hydrogenation by using transmission electron microscopy (TEM), and then to clarify the catalytic effect [2]. Futhermore, the relationship between desorption properties and lithium ionic mobility has been identified by using AC-impedance method [3].
References
1.P. Chen, Z. Xiong, J. Z. Luo, J. Y. Lin, K. L. Tan, Nature 420 (2002) 302.
2.T. Zhang, S. Isobe, Y. Wang, N. Hashimoto and S. Ohnuki, ChemCatChem 6 (3) (2014) 724.
3.T. Zhang, S. Isobe, Y. Wang. M. Matsuo, S. Orimo, N. Hashimoto and S. Ohnuki, ACS Catal. 5 (2015) 1552.